Transition metal complexes of isatin monoxime
Shaymaa Adawy Mohamed Hassan;
Abstract
The present thesis entitled ¨Transition metal complexes of isatin-3-oxime¨ comprises three chapters.
Chapter one:-
This chapter concerned with concepts, preparation, modes of bonding, importance and metal complexes of oximes. It also includes the literature survey on the preparation of isatin-3-oxime ligand and its transition metal complexes.
Chapter two:-
This chapter is related to the experimental part, the list of chemicals and different standardized instruments (such as UV-Vis, 1HNMR, IR, magnetic Gouy balance, pH, TGA and conductivity) that are used in synthesis, characterization and investigation of the ligand and its complexes. Di-µ-oxo bimolybdenum complex of general formula Mo2O4- (H2ISMO)2(THF)2 ( THF= tetrahydrofuran) was synthesized in two steps starting with the reaction of Mo(CO)6 with 2,2'- bipyridine then followed by the addition of isatin-3-oxime ligand. Moreover, dichromuim oxo complex of general formula Cr2O4(H2ISMO)2 was prepared in high yield by the reaction of chromium hexa carbonyl with H2ISMO in sun light.
Chapter one:-
This chapter concerned with concepts, preparation, modes of bonding, importance and metal complexes of oximes. It also includes the literature survey on the preparation of isatin-3-oxime ligand and its transition metal complexes.
Chapter two:-
This chapter is related to the experimental part, the list of chemicals and different standardized instruments (such as UV-Vis, 1HNMR, IR, magnetic Gouy balance, pH, TGA and conductivity) that are used in synthesis, characterization and investigation of the ligand and its complexes. Di-µ-oxo bimolybdenum complex of general formula Mo2O4- (H2ISMO)2(THF)2 ( THF= tetrahydrofuran) was synthesized in two steps starting with the reaction of Mo(CO)6 with 2,2'- bipyridine then followed by the addition of isatin-3-oxime ligand. Moreover, dichromuim oxo complex of general formula Cr2O4(H2ISMO)2 was prepared in high yield by the reaction of chromium hexa carbonyl with H2ISMO in sun light.
Other data
| Title | Transition metal complexes of isatin monoxime | Other Titles | متراكبات العناصر الانتقاليه مع الاساتين احادي الاكسيم | Authors | Shaymaa Adawy Mohamed Hassan | Issue Date | 2014 |
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