Group VI dinuclear oxo metal complexes of salicylideneimine-2-anisole schiff base
Ali, Omyma; Mostafa M. H. Khalil; Gehad M. Attia; Ramadan M. Ramadan;
Abstract
Interaction of the Schiff base salicylideneimine-2-anisole (salanH) with
Cr(CO)6 yielded the dicarbonyl derivative Cr2O2(CO)2(salan)2. The
dinuclear oxo complex M2O4(salan)2, M=Mo and W, was isolated from
the reaction of M(CO)6 with salanH. Elemental, spectroscopic and
magnetic studies of the reported complexes allowed structures to be
proposed. The thermal properties of the complexes were investigated
by thermogravimetry.
Cr(CO)6 yielded the dicarbonyl derivative Cr2O2(CO)2(salan)2. The
dinuclear oxo complex M2O4(salan)2, M=Mo and W, was isolated from
the reaction of M(CO)6 with salanH. Elemental, spectroscopic and
magnetic studies of the reported complexes allowed structures to be
proposed. The thermal properties of the complexes were investigated
by thermogravimetry.
Other data
| Title | Group VI dinuclear oxo metal complexes of salicylideneimine-2-anisole schiff base | Authors | Ali, Omyma ; Mostafa M. H. Khalil ; Gehad M. Attia ; Ramadan M. Ramadan | Issue Date | 2003 | Publisher | Taylor and Francis | Journal | Spectroscopy Letters |
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