Characteristics of Dielectric Behavior and AC Electrical Conductivity of Bulk Antimony Sulfide (Sb2S3)
El-Sayed, hamed; Ali, Hend; G.F.Salem; Mahmoud, Mohamed;
Abstract
The structural features and morphology of investigated Sb2S3 powder were analyzed using X-ray
diffraction and scanning electron microscope techniques. The dependence of dielectric properties and ac
conductivity of bulk Sb2S3 as pellet on both of frequency (102
–106 Hz) and temperature (303-393 K) were
studied. The dielectric constant (121.2-45.8) and dielectric loss (53.3-0.89) displayed noticeable
dependence on frequency and in the investigated range of temperature 303-393 K. The frequency
dependence of ac conductivity σac(ω) follows up the power relation; σac(ω) = Gωs
. The frequency
exponent s, diminished with the rise in temperature, implying that the correlated barrier hopping (CBH)
is the predominant conduction mechanism. The ac conductivity exhibited a thermally activated nature.
The localized states N(EF) values were recorded in the order of 1018 eV-1
.cm-3
at specific temperatures for
frequency of 800 Hz. Activation energy ΔE, calculated at different frequencies indicates a decrease from
117 meV to 89 meV with the increase in the frequency.
diffraction and scanning electron microscope techniques. The dependence of dielectric properties and ac
conductivity of bulk Sb2S3 as pellet on both of frequency (102
–106 Hz) and temperature (303-393 K) were
studied. The dielectric constant (121.2-45.8) and dielectric loss (53.3-0.89) displayed noticeable
dependence on frequency and in the investigated range of temperature 303-393 K. The frequency
dependence of ac conductivity σac(ω) follows up the power relation; σac(ω) = Gωs
. The frequency
exponent s, diminished with the rise in temperature, implying that the correlated barrier hopping (CBH)
is the predominant conduction mechanism. The ac conductivity exhibited a thermally activated nature.
The localized states N(EF) values were recorded in the order of 1018 eV-1
.cm-3
at specific temperatures for
frequency of 800 Hz. Activation energy ΔE, calculated at different frequencies indicates a decrease from
117 meV to 89 meV with the increase in the frequency.
Other data
Title | Characteristics of Dielectric Behavior and AC Electrical Conductivity of Bulk Antimony Sulfide (Sb2S3) | Authors | El-Sayed, hamed; Ali, Hend ; G.F.Salem ; Mahmoud, Mohamed | Keywords | Antimony sulfide;AC electrical conductivity;Dielectric properties;Density of localized states | Issue Date | 2020 | Publisher | (2020 | Journal | Arab Journal of Nuclear Sciences and Applications | Volume | 53 | Issue | 4 | Start page | 93 | End page | 101 | ISSN | 2090-4258 | DOI | 10.21608/ajnsa.2020.27596.1344 |
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