Electrochemical studies of Some Schiff-Base Complexes Prepared By Sacrificied Anodes

Abstract

The thesis mainly comprises three chapters :- I- Introduction In this chapter, a literature survey was made on the history of the

Schiff-base complexes of hydrazone derivatives.

II -Experimental

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In this chapter, the methods used for preparation of the ligands and their Cu(II), Co(II) and Ni(II) complexes were described . The techniques and equipments used for analytical, spectral, magnetic and electrochemical measurements were also reported.

III - Results and discussion

This chapter is subdivided into two main parts

First part

This part includes the characterization of Cu(II), Co(II) and Ni(II)

complexes of ligands 1-5.

The analytical, spectral and magnetic data show that L 1 reacts with copper sheet in acetone and acetonitrile to give the corresponding metal complexes with composition 1:2 (metal: ligand) while in the presence