A manganese-based coordination polymer; synthesis, structure and catalytic activity
Alghool, Samir; Slebodnick, Carla; Khaled, Khaled F.;
Abstract
A two-dimensional manganese(II)-based coordination polymer [Mn(L)4(CH3COO)2] [L=1,4-bis(1-imidazolyl)benzene] has been synthesised. Its X-ray structure revealed that the layers of the 2D structure are stacked together by two types of weak interactions extending to form a three-dimensional supramolecular structure. The thermal stability of this coordination polymer is described and the compound has been used as a heterogeneous catalyst in oxidation of cyclohexene to cyclohexene oxide. A density functional study of structural parameters, position of the HOMO and LUMO energies, electrophilicity and global hardness is reported.
Other data
| Title | A manganese-based coordination polymer; synthesis, structure and catalytic activity | Authors | Alghool, Samir; Slebodnick, Carla; Khaled, Khaled F. | Keywords | Cyclohexene;Heterogeneous catalysis;Thermal stability;Supramolecular structure;Manganese(II) coordination polymer | Issue Date | 1-Jul-2016 | Journal | Journal of Chemical Research | ISSN | 17475198 | DOI | 10.3184/174751916X14655773247783 | Scopus ID | 2-s2.0-84978435459 |
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