Unanticipated Heterocyclization from Reaction of Hydrazine Hydrate and/or Hydrazine Dihydrochloride with 1-Ethyl-4-hydroxyquinolin-2(1H)- one

Hassan, Heba;

Abstract


Unexpectedly, the reaction of 1-ethyl-4-hydroxyquinolin-2(1H)-one (1) with hydrazine hydrate and/or
hydrazine dihydrochloride led to three different products. In addition to the expected quninolinylhydrazine,
two heteropentacycles, diquinopyrrole and diquinopyridazine, were afforded, depending on reaction conditions.
The structure of the new products was established upon their spectral and analytical data.


Other data

Title Unanticipated Heterocyclization from Reaction of Hydrazine Hydrate and/or Hydrazine Dihydrochloride with 1-Ethyl-4-hydroxyquinolin-2(1H)- one
Authors Hassan, Heba 
Issue Date 16-Dec-2018
Journal Journal of Heterocyclic Chemistry 
Volume 56
Start page 646
DOI 10.1002/jhet.3443

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