Fourier-transform infrared and electrical properties of magnesium phthalocyanine thin films
El-Nahass, M. M.; Atta, A. A.; E.F.M.El-Zaidia;
Abstract
The Fourier-transform infrared (FT-IR) spectra of magnesium phthalocyanine (MgPc) were investigated in the spectral range 500-4000 cm-1. The spectra allow characterization of vibration modes. A comparison of absorption spectra of powder, as-deposited and annealed films is presented. The dark electrical resistivity measurements were carried out at different temperatures in the range 308 to 423 K. Two activation energies ΔE1 = 0.23 eV and ΔE2 = 0.69 eV were obtained. The thermal activation energy ΔE1 is associated with impurity conduction and ΔE2 is associated with intrinsic conduction. The current density-voltage characteristics of MgPc at room temperature showed a linear ohmic conduction mechanism at low voltages. At higher voltages the space-charge-limited conduction (SCLC) accompanied as a single dominant level. The temperature dependence of current density allows the determination of some essential parameters such as the hole mobility (μh), the trapping factor Θ and the total trap concentration (Nt). © EDP Sciences, 2011.
Other data
Title | Fourier-transform infrared and electrical properties of magnesium phthalocyanine thin films | Authors | El-Nahass, M. M.; Atta, A. A.; E.F.M.El-Zaidia | Keywords | COPPER PHTHALOCYANINE;TEMPERATURE;CELLS | Issue Date | 1-Apr-2011 | Publisher | EDP SCIENCES S A | Journal | EPJ Applied Physics | ISSN | 12860042 | DOI | 10.1051/epjap/2011100355 | Scopus ID | 2-s2.0-79959652609 | Web of science ID | WOS:000289624000004 |
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