Synthesis and Characterization of Some New Binary and Ternary Copper Complexes: X-Ray Crystal Structural of Dioxo Dinuclear Bipyridine Copper Complex
Ramadan, Ramadan M.; Shohayeb, SM; Mohamed RG;
Abstract
Binary and ternary copper complexes were synthesized from the reactions of Cu(NO3)2, amino acids (N-acetylvaline, av, N- acetylphenylalanine, apa, and N-acetyltryptophan, atp), and heterocyclic nitrogen ligands (2,2′-bipyridine, bpy, and 1,10-phenanthroline, phen). The complexes have been characterized by elemental analysis, IR, EPR, and mass spectrometry. The dioxo dinuclear bipyridine copper complex was studied by X-ray structure analysis. The analysis revealed that it crystallized in the triclinic space group P1 with a Z value of 1. The crystal packing showed three-dimensional supramolecular arrangements of the molecules stabilized by intra- and intermolecular hydrogen bonds. Copyright © Taylor and Francis Group, LLC.
Other data
Title | Synthesis and Characterization of Some New Binary and Ternary Copper Complexes: X-Ray Crystal Structural of Dioxo Dinuclear Bipyridine Copper Complex | Authors | Ramadan, Ramadan M. ; Shohayeb, SM; Mohamed RG | Keywords | 2;amino acids;2bipyridine;copper complexes;crystal structure;EPR analysis;SUPEROXIDE-DISMUTASE;MAGNETIC-PROPERTIES;LIGANDS;2-(2'-PYRIDYL)BENZIMIDAZOLE;2,2'-BIPYRIDINE;MONONUCLEAR;RUTHENIUM;ADDUCTS;MODEL;ACID | Issue Date | 2013 | Publisher | TAYLOR & FRANCIS INC | Journal | Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry | Volume | 43 | Issue | 5 | Start page | 609 | End page | 616 | ISSN | 1553-3174 | DOI | 10.1080/15533174.2012.752390 | Scopus ID | 2-s2.0-84875928480 | Web of science ID | WOS:000316070000015 |
Recommend this item
Similar Items from Core Recommender Database
Items in Ain Shams Scholar are protected by copyright, with all rights reserved, unless otherwise indicated.