New Designs for Chemical Ion Sensors and Their Use in Environmental and Industrial Applications

Abstract

- The thesis content can be portrayed briefly as three chapters:  Chapter (I): General introduction: - It illustrates the main principles and components of ISEs, an overview about solid-contact ion-selective electrodes, the difficulties facing some types of ISEs, limitations of conventional and coated wire ISEs, and Challenges in potentiometric solid-contact ion selective electrodes. -  Chapter (II): Single-Piece All-Solid-State Potential Ion-Selective Electrodes Integrated with Molecularly Imprinted Polymers (MIPs) for Neutral 2,4-Dichlorophenol Assessment: - A novel single-piece all-solid-state ion-selective electrode (SC/ISE) based on carbon-screen printed is introduced. Polyaniline (PANI) is dissolved in a membrane cocktail that contains the same components used for making a conventional ion-selective polyvinyl chloride (PVC) matrix membrane. The membrane, having the PANI, is directly drop-casted on a carbon substrate (screen-printed-carbon electrode). PANI was added to act as an intermediary between the substrate and the membrane for the charge transfer process. Under non-equilibrium sensing mechanism, the sensors revealed high sensitivity towards 2,4-dichlorophenol (DCP) over the linearity range 0.47 to 13 µM and a detection limit 0.13 µm. The selectivity was measured by the modified separate solution method (MSSM) and showed good selectivity towards 2,4-DCP over the most commonly studied ions. All measurements were done in 30 mm Tris buffer solution at a pH 5.0. Using constant-current chronopotentiometry, the potential drift for the proposed electrodes was