Design and synthesis of novel bichalcophene derivatives with double anchoring groups for dye-sensitized solar cell applications: sensitization and co-sensitization with N-719
Abdelhamed, Fatma H.; Ismail, Mohamed A; Abdel-Latif, Ehab; Abdel-Shafi, Ayman; Elmorsy, Mohamed R.;
Abstract
Novel dyes F1-3 based on bichalcophene-pyrimidine-2,4,6-trione derivatives with dual anchoring were developed, synthesized, and evaluated as sensitizers and co-sensitizers for dye-sensitized solar cells (DSSCs). F1 displayed the best DSSC performance (η, PCE = 4.41%) and the highest photovoltaic parameters, which were as follows: current density, JSC = 10.66 mA cm−2, photovoltage, VOC = 0.654 V, and fill factor, FF = 64.3%. These findings can be ascribed to F1’s superior optical and electrochemical characteristics when compared to other structures such as F2 and F3. Interestingly, devices that rely on the F1 + N-719 co-sensitization approach had greater photocurrent and photovoltage than the standard N-719 dye, generating a power conversion efficiency (PCE) of 9.97%. This improved performance was mostly due to a higher JSC value of 23.28 mA cm−2 for the dye F1 and a maximum molar extinction coefficient in the 350–550 nm region, which enhanced the light-harvesting capacity of the N-719 dye.
Other data
Title | Design and synthesis of novel bichalcophene derivatives with double anchoring groups for dye-sensitized solar cell applications: sensitization and co-sensitization with N-719 | Authors | Abdelhamed, Fatma H.; Ismail, Mohamed A ; Abdel-Latif, Ehab; Abdel-Shafi, Ayman ; Elmorsy, Mohamed R. | Issue Date | 1-Jul-2022 | Journal | Journal of Materials Science: Materials in Electronics | Volume | 33 | Start page | 15665 | End page | 15678 | ISSN | 09574522 | DOI | 10.1007/s10854-022-08470-9 | Scopus ID | 2-s2.0-85131557586 |
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