Structural and magnetic properties of ferromagnetic nano-sized (Ni 1-xCox)0.85Se prepared by simple hydrothermal method

Heiba, zein Elabidin; Mostafa, Nasser Y.; Mohamed, Mohamed Bakr; Al-Harthi, H.;

Abstract


Nanocrystalline (Ni1-xCox)0.85Se with 0.0≤x≤1 solid solutions were prepared by a simple hydrothermal route. All samples form a NiAs-type hexagonal structure with metal vacancies. From Rietveld analysis, the lattice parameters are found to decrease nonlinearly with composition x; crystallite size and microstrain vary anisotropically. Magnetic measurements show that Ni0.85Se and Co0.75Se samples exhibit ferromagnetic properties while (Ni0.5Co0.5) 0.85Se shows a paramagnetic behavior at room temperature. For the first time, nano-Ni0.85Se is reported to be ferromagnetic. © 2012 Published by Elsevier B.V. All rights reserved.


Other data

Title Structural and magnetic properties of ferromagnetic nano-sized (Ni <inf>1-x</inf>Co<inf>x</inf>)<inf>0.85</inf>Se prepared by simple hydrothermal method
Authors Heiba, zein Elabidin ; Mostafa, Nasser Y.; Mohamed, Mohamed Bakr; Al-Harthi, H.
Keywords Chalcogenides;Crystal structure;Magnetic materials;Nanosize
Issue Date 7-Jan-2013
Journal Materials Letters 
Volume 93
Start page 115
End page 117
ISSN 0167577X
DOI 10.1016/j.matlet.2012.11.079
Scopus ID 2-s2.0-84871808389

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