Group VI dinuclear oxo metal complexes of salicylideneimine-2-anisole Schiff base

Ali, Omyma A.M.; Khalil, M.M.H.; Attia, Gehad M.; Ramadan, Ramadan M.;

Abstract


Interaction of the Schiff base salicylideneimine-2-anisole (salanH) with Cr(CO)6 yielded the dicarbonyl derivative Cr2O2(CO)2(salan)2. The dinuclear oxo complex M2O4(salan)2, M = Mo and W, was isolated from the reaction of M(CO)6 with salanH. Elemental, spectroscopic and magnetic studies of the reported complexes allowed structures to be proposed. The thermal properties of the complexes were investigated by thermogravimetry.


Other data

Title Group VI dinuclear oxo metal complexes of salicylideneimine-2-anisole Schiff base
Authors Ali, Omyma A.M.; Khalil, M.M.H. ; Attia, Gehad M.; Ramadan, Ramadan M.
Keywords Chromium | Complexes | IR spectra | Metal carbonyls | Schiff bases | Thermal analysis
Issue Date 16-Jun-2003
Publisher MARCEL DEKKER INC
Journal Spectroscopy Letters 
Volume 36
Issue 1-2
Start page 71
End page 82
ISSN 00387010
DOI 10.1081/SL-120021174
Scopus ID 2-s2.0-0037977861
Web of science ID WOS:000183290000007

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