Molybdenum and tungsten tricarbonyl complexes of isatin with triphenylphosphine
Khalil, M.M.H.; Al-Seif, F. A.;
Abstract
Reaction of M(CO)6; M = Mo or W with isatin in the presence of triphenylphosphine in THF under reduced pressure gave the tricarbonyl derivatives complexes [M(CO)3(isatH)(PPh3)]. The two complexes were characterized by elemental analysis, infrared, mass and 1H NMR spectroscopy. The spectroscopic studies show that the two complexes exist in fac- and mer-isomers in solutions through exchange the CO group and PPh3. The Uv-Vis spectra of the complexes in different solvents were studied.
Other data
| Title | Molybdenum and tungsten tricarbonyl complexes of isatin with triphenylphosphine | Authors | Khalil, M.M.H. ; Al-Seif, F. A. | Issue Date | 1-Jan-2010 | Journal | Inorganic Chemistry: Reactions, Structure and Mechanisms | Volume | 14 | Issue | 1 | Start page | 33 | End page | 39 | ISBN | 9781466559776 | Scopus ID | 2-s2.0-85059561889 |
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